Instant yeast tends to be very aggressive/successful so what happens if you use a small amount of instant yeast is you get a slow rise but it's a monoculture microbially speaking versus if you use a typical sourdough starter (called "madre" in Italian baking) there are several strains of bacteria which are about equivalent in terms of how fast they multiply. So the final dough has a more diverse microbiome. The theory is that leads to a more complex taste because of the way the different yeast strains digest the sugars etc and affect the taste of the resulting product.
Definitely agree in regards to sourdough starter vs yeast. Although I thought most Neapolitan pizzerias didn't use sourdough anyways - would love to be wrong about this.